3) Cristiano Ronaldo (Real Madrid) v Manchester United – 2013
Ronaldo came up against his former side for the first time following his £80 million deal to take him to Spain in 2009.
A bullet header just when Real needed it as United had taken the lead through their then striker Danny Welbeck.
Ronaldo would go on again to score the decisive goal of the tie in the return leg at Old Trafford.