5. Valentino Mazzola – Italy
Mazzola captained the great Torino side of the 1940?s, before he was tragically killed in the Superga air disaster in 1949.
The influential attacking midfielder became famous for rolling up his shirt sleeves to signal when his team were under-performing.
He only represented Italy 12 times, between 1942 and 1949, scoring four goals for the Azzurri.